Serveur d'exploration sur le cobalt au Maghreb

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AgCo3PO4(HPO4)2

Identifieur interne : 000B41 ( Main/Exploration ); précédent : 000B40; suivant : 000B42

AgCo3PO4(HPO4)2

Auteurs : Abderrahmen Guesmi [Tunisie] ; Ahmed Driss [Tunisie]

Source :

RBID : Pascal:02-0230954

Descripteurs français

English descriptors

Abstract

The structure of the hydrothermally synthesized compound AgCo3PO4(HPO4)2, silver tricobalt phosphate bis(hydrogen phosphate), consists of edge-sharing CoO6 chains linked together by the phosphate groups and hydrogen bonds. The three-dimensional framework delimits two types of tunnels which accommodate Ag+ cations and OH groups. The title compound is isostructural with the compounds AM3H2(XO4)3 (A = Na or Ag, M = Co or Mn, and X = P or As) of the alluaudite structure type.


Affiliations:


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Le document en format XML

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<fileDesc>
<titleStmt>
<title xml:lang="en" level="a">AgCo
<sub>3</sub>
PO
<sub>4</sub>
(HPO
<sub>4</sub>
)
<sub>2</sub>
</title>
<author>
<name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
<affiliation wicri:level="3">
<inist:fA14 i1="01">
<s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1>
<s2>Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<placeName>
<settlement type="city">Tunis</settlement>
<region nuts="2">Gouvernorat de Tunis</region>
</placeName>
<placeName>
<settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
</placeName>
<orgName type="university" n="3">Université de Tunis - El Manar</orgName>
</affiliation>
</author>
<author>
<name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
<affiliation wicri:level="3">
<inist:fA14 i1="01">
<s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1>
<s2>Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<placeName>
<settlement type="city">Tunis</settlement>
<region nuts="2">Gouvernorat de Tunis</region>
</placeName>
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</author>
</titleStmt>
<publicationStmt>
<idno type="wicri:source">INIST</idno>
<idno type="inist">02-0230954</idno>
<date when="2002">2002</date>
<idno type="stanalyst">PASCAL 02-0230954 INIST</idno>
<idno type="RBID">Pascal:02-0230954</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000254</idno>
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<sourceDesc>
<biblStruct>
<analytic>
<title xml:lang="en" level="a">AgCo
<sub>3</sub>
PO
<sub>4</sub>
(HPO
<sub>4</sub>
)
<sub>2</sub>
</title>
<author>
<name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
<affiliation wicri:level="3">
<inist:fA14 i1="01">
<s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1>
<s2>Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<placeName>
<settlement type="city">Tunis</settlement>
<region nuts="2">Gouvernorat de Tunis</region>
</placeName>
<placeName>
<settlement type="city">Tunis</settlement>
<region type="region" nuts="2">Gouvernorat de Tunis</region>
</placeName>
<orgName type="university" n="3">Université de Tunis - El Manar</orgName>
</affiliation>
</author>
<author>
<name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
<affiliation wicri:level="3">
<inist:fA14 i1="01">
<s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1>
<s2>Tunis</s2>
<s3>TUN</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<placeName>
<settlement type="city">Tunis</settlement>
<region nuts="2">Gouvernorat de Tunis</region>
</placeName>
</affiliation>
</author>
</analytic>
<series>
<title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
<imprint>
<date when="2002">2002</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt>
<title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title>
<title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title>
<idno type="ISSN">0108-2701</idno>
</seriesStmt>
</fileDesc>
<profileDesc>
<textClass>
<keywords scheme="KwdEn" xml:lang="en">
<term>Channel structure</term>
<term>Cobalt Acid phosphates</term>
<term>Cobalt phosphates</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Hydrogen bonds</term>
<term>Hydrothermal synthesis</term>
<term>Silver Acid phosphates</term>
<term>Silver phosphates</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Etude expérimentale</term>
<term>Synthèse hydrothermale</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Argent phosphate</term>
<term>Argent Hydrogénophosphate</term>
<term>Cobalt phosphate</term>
<term>Cobalt Hydrogénophosphate</term>
<term>Liaison hydrogène</term>
<term>Structure tunnel</term>
<term>6166F</term>
<term>AgCo3PO4(HPO4)2</term>
<term>Ag Co H O P</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front>
<div type="abstract" xml:lang="en">The structure of the hydrothermally synthesized compound AgCo
<sub>3</sub>
PO
<sub>4</sub>
(HPO
<sub>4</sub>
)
<sub>2</sub>
, silver tricobalt phosphate bis(hydrogen phosphate), consists of edge-sharing CoO
<sub>6</sub>
chains linked together by the phosphate groups and hydrogen bonds. The three-dimensional framework delimits two types of tunnels which accommodate Ag
<sup>+</sup>
cations and OH groups. The title compound is isostructural with the compounds AM
<sub>3</sub>
H
<sub>2</sub>
(XO
<sub>4</sub>
)
<sub>3</sub>
(A = Na or Ag, M = Co or Mn, and X = P or As) of the alluaudite structure type.</div>
</front>
</TEI>
<affiliations>
<list>
<country>
<li>Tunisie</li>
</country>
<region>
<li>Gouvernorat de Tunis</li>
</region>
<settlement>
<li>Tunis</li>
</settlement>
<orgName>
<li>Université de Tunis - El Manar</li>
</orgName>
</list>
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<country name="Tunisie">
<region name="Gouvernorat de Tunis">
<name sortKey="Guesmi, Abderrahmen" sort="Guesmi, Abderrahmen" uniqKey="Guesmi A" first="Abderrahmen" last="Guesmi">Abderrahmen Guesmi</name>
</region>
<name sortKey="Driss, Ahmed" sort="Driss, Ahmed" uniqKey="Driss A" first="Ahmed" last="Driss">Ahmed Driss</name>
</country>
</tree>
</affiliations>
</record>

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{{Explor lien
   |wiki=    Wicri/Terre
   |area=    CobaltMaghrebV1
   |flux=    Main
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   |type=    RBID
   |clé=     Pascal:02-0230954
   |texte=   AgCo3PO4(HPO4)2
}}

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